pH Calculator
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The pH scale fundamentally changed how we understand and measure acidity and alkalinity in our world. Introduced in 1909 by Danish chemist Søren Peter Lauritz Sørensen while working at Carlsberg Laboratory (yes, the brewery!), the term "pH" stands for "potential of hydrogen" or "power of hydrogen." What began as a brewing science concept has become essential across countless scientific fields, from medicine and environmental science to agriculture and food production.
At its core, pH measures the concentration of hydrogen ions (H⁺) in a solution. The scale is logarithmic, meaning each whole pH value represents a tenfold change in acidity or alkalinity. This logarithmic nature allows us to express a wide range of concentrations—from strong acids to strong bases—using a simple 0-14 scale.
These mathematical relationships allow scientists to precisely calculate hydrogen ion and hydroxide ion concentrations, essential values in chemistry, biology, and environmental sciences. The water dissociation constant (Kw) represents the product of hydrogen and hydroxide ion concentrations in water, which remains constant at a given temperature.
Higher concentration of H⁺ ions than OH⁻ ions
Equal concentration of H⁺ and OH⁻ ions
Higher concentration of OH⁻ ions than H⁺ ions
Buffer solutions resist pH changes when acids or bases are added, making them essential in biological systems and laboratory work. These solutions typically contain a weak acid and its conjugate base (like acetic acid/acetate) or a weak base and its conjugate acid (like ammonia/ammonium). The human body contains several buffer systems, including the bicarbonate buffer in blood, that maintain our critical pH balance.
The development of pH theory and measurement techniques represents one of the most impactful advances in analytical chemistry. Before Sørensen's work, scientists struggled to precisely quantify acidity. His pH scale provided a standardized approach that has remained relevant for over a century, enabling countless scientific discoveries across disciplines. The concept has expanded beyond hydrogen ions to other ions and molecules (pK, pOH, etc.), demonstrating the fundamental nature of the logarithmic concentration approach to scientific measurement.
Temperature affects the water dissociation constant (Kw), which changes the relationship between pH and pOH. At 25°C, pH + pOH = 14, but this sum varies with temperature. The calculator automatically adjusts for temperature effects.
Buffer capacity (β) measures a buffer's ability to resist pH changes when acids or bases are added. It's defined as the number of moles of H+ or OH- needed to change the pH by one unit. Higher values indicate stronger buffering action.
A good buffer has approximately equal concentrations of acid and conjugate base, and its pKa should be within ±1 unit of the desired pH. The total concentration should be high enough to provide adequate buffering capacity without causing other chemical effects.